Solution‐Processed Efficient Organic Upconversion Device for Direct NIR Imaging

Author:

Dong Shilong1,Zhang Yi12,Wang Zehong1,Li Jin1,Zhou Zichun1,Zhu Lei1,Zhong Hongliang1,Liu Feng1,Jiang Xuesong1ORCID

Affiliation:

1. School of Chemistry & Chemical Engineering Frontiers Science Center for Transformative Molecules State Key Laboratory for Metal Matrix Composite Materials Shanghai Jiao Tong University Shanghai 200240 China

2. Key Laboratory of Green and Precise Synthetic Chemistry and Applications Ministry of Education Department of Chemistry Huaibei Normal University Huaibei 235000 China

Abstract

AbstractInfrared upconversion devices (UCDs) enable NIR imaging without array and readout circuits, making them desirable for portable sensor, imaging and monitoring. However, the exorbitant cost and difficulties in fabrication associated with vacuum‐deposited materials, which are usually employed in high‐performance UCDs, restrict their application in flexible‐stretchable systems. Here, a solution‐processed upconversion device (s‐UCD), which is composed of detector and emitter, with high conversion efficiency and low turn‐on voltage achieved by device structure design and interlayer engineering is reported. The role of the electron blocking layer is investigated in s‐UCDs, and a peak luminance of 5,500 cd m−2 @7 V and a luminance on‐off ratio of 110000 @5.25 V are achieved. The s‐UCDs exhibit high resolution, microsecond response time and are compatible with flexible substrates. With the high‐performance large‐area s‐UCDs, direct non‐invasive transmission‐based bioimaging applications with high quality of bioimaging are further performed. It is believed that the s‐UCD imaging system offers potential applications for portable low‐cost non‐invasive tissue analysis, disease diagnosis, and virtual reality.

Funder

National Natural Science Foundation of China

Publisher

Wiley

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