Positioning solvolyses within the SN2-SN1 and SN3-SN2 spectrum of reaction mechanisms-Reference-Cited by-同舟云学术

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Positioning solvolyses within the SN2-SN1 and SN3-SN2 spectrum of reaction mechanisms

Published:2016-06-01 Issue:1 Volume:30 Page:e3585
ISSN:0894-3230
Container-title:Journal of Physical Organic Chemistry
language:en
Short-container-title:J. Phys. Org. Chem.

Author:

Bentley T. W.¹,Choi Hojune²,Koo In Sun²,Kevill Dennis N.³

Affiliation:

1. Chemistry Unit, Grove Building, College of Medicine; Swansea University; Swansea SA2 8PP UK

2. Department of Chemical Education and Research Institute of Natural Science; Gyeongsang National University; Jinju 660-701 Korea

3. Department of Chemistry and Biochemistry; Northern Illinois University; DeKalb IL 60115-2862 USA

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

Reference65 articles.

1. SN1-SN2 and SN2-SN3 mechanistic changes revealed by transition states of the hydrolyses of benzyl chlorides and benzenesulfonyl chlorides

2. Solvent Effects on the Solvolysis ofp-Nitrobenzyl and 3,5-Bis(trifluoromethyl)benzylp-Toluenesulfonates

3. Correlation of the rates of solvolysis of arylmethyl p-toluenesulfonates: application of the aromatic ring parameter and a discussion of similarity models

4. The SN3-SN2 spectrum. Rate constants and product selectivities for solvolyses of benzenesulfonyl chlorides in aqueous alcohols

5. Concerted SN 2 mechanism for the hydrolysis of acid chlorides: comparisons of reactivities calculated by the density functional theory with experimental data

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1. Exploring borderline S_N1–S_N2 mechanisms: the role of explicit solvation protocols in the DFT investigation of isopropyl chloride;RSC Advances;2024

2. Nucleophilic Aliphatic Substitution;Organic Reaction Mechanisms Series;2020-07-24

3. Formation of S-alkyl thiophenium ionic liquids: mechanistic rationale and structural relationships;Organic & Biomolecular Chemistry;2019

4. Mutual Kinetic Resolution of Racemic 3,4-Dihydro-3-methyl-2H -[1,4]benzoxazines with Acyl Chlorides of Racemic O -Phenyllactic Acids and DFT Modelling of Transition States;European Journal of Organic Chemistry;2018-08-17

5. Mechanistic Study of the Solvolysis of Piperidine-1-sulfonyl chloride in Binary Solvent Mixtures;Bulletin of the Korean Chemical Society;2017-09

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