SN1-SN2 and SN2-SN3 mechanistic changes revealed by transition states of the hydrolyses of benzyl chlorides and benzenesulfonyl chlorides
Author:
Affiliation:
1. Fukui Institute for Fundamental Chemistry, Kyoto University; Takano-Nishihiraki-cho 34-4 Sakyo-ku Kyoto 606-8103 Japan
Publisher
Wiley
Subject
Computational Mathematics,General Chemistry
Link
http://onlinelibrary.wiley.com/wol1/doi/10.1002/jcc.23607/fullpdf
Reference37 articles.
1. The Correlation of Solvolysis Rates
2. 55. Mechanism of substitution at a saturated carbon atom. Part IV. A discussion of constitutional and solvent effects on the mechanism, kinetics, velocity, and orientation of substitution
3. The SN2-SN1 spectrum. 1. Role of nucleophilic solvent assistance and nucleophilically solvated ion pair intermediates in solvolyses of primary and secondary arenesulfonates
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