Microstructural evolution of layered K‐doped RuCl<sub>3</sub> during annealing traced by thermogravimetric analysis and 3D electron diffraction-Reference-Cited by-同舟云学术

Microstructural evolution of layered K‐doped RuCl₃ during annealing traced by thermogravimetric analysis and 3D electron diffraction

Published:2023-08-22 Issue:19 Volume:649 Page:
ISSN:0044-2313
Container-title:Zeitschrift für anorganische und allgemeine Chemie
language:en
Short-container-title:Zeitschrift anorg allge chemie

Author:

Vinokurova Ekaterina¹²,Knorr Monika³^ORCID,Efimova Anastasia³^ORCID,Ovchinnikov Alexander²^ORCID,Schmidt Peer³^ORCID,Büchner Bernd¹^ORCID,Isaeva Anna¹⁴^ORCID,Roslova Maria¹^ORCID

Affiliation:

1. Leibniz Institute for Solid State and Materials Research Dresden Helmholtzstraße 20 01069 Dresden Germany

2. Technische Universität Dresden Haeckelstraße 3 01062 Dresden Germany

3. Brandenburgische Technische Universität Cottbus-Senftenberg Universitätsplatz 1 01968 Senftenberg Germany

4. University of Amsterdam Science Park 904 1098 XH Amsterdam, The Netherlands

Abstract

AbstractNanoscale phase separation was induced in the K‐doped RuCl3 van der Waals material by annealing, and studied with the goal to find a natural design strategy for the formation of two‐dimensional architectures as an alternative to the costly and time‐consuming experimental artificial growth methods. Phase conversion was traced by means of thermogravimetric analysis combined with mass spectrometry. The local crystal structure of co‐existing K3Ru2Cl9 domains with the sizes of about 100 nm was solved by 3D electron diffraction.

Funder

Deutsche Forschungsgemeinschaft

European Regional Development Fund

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.202300141

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