Synthesis and characterization of low dielectric constant polybenzoxazines with different fluorine contents

Author:

Ma Xiaoyun1,Lu Xin1,Yuan Manlin1,Lin Hao1,Pan Xinyi1,Kuo Shiao‐Wei2,Xin Zhong1ORCID

Affiliation:

1. State Key Laboratory of Chemical Engineering, School of Chemical Engineering East China University of Science and Technology Shanghai People's Republic of China

2. Department of Materials and Optoelectronic Science National Sun Yat‐Sen University Kaohsiung Taiwan

Abstract

AbstractThe rapid development of integrated circuits puts forward higher requirements for low dielectric constant polymers. In this study, two fluorinated benzoxazine monomers, bis‐(3,4‐dihydro‐3‐(4‐fluoro‐3‐(trifluoromethyl)phenyl)‐2H‐1,3‐benzoxazine)isopropane (BA‐ftfa) and bis‐(3,4‐dihydro‐3‐(4‐fluoro‐3‐(trifluoromethyl)phenyl)‐2H‐1,3‐benzoxazine)isoperfluoropropane (BAF‐ftfa), were successfully synthesized. Differential scanning calorimeter (DSC) was used to monitor the thermal curing behaviors of the monomers and their mixtures. Five groups of polybenzoxazine samples with different fluorine content (25% ~ 35%) were obtained by copolymerizing the two monomers with different mass ratios. The effects of fluorine content on dielectric properties were investigated and the results show that PBAF‐ftfa with the highest fluorine content has the lowest dielectric constant of 2.53 at 1 MHz. Furthermore, the results of thermogravimetric analysis (TGA) and dynamic mechanical analysis (DMA) show that all polymers possess excellent thermal stability and exhibit high glass transition temperatures over than 180°C.

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,Surfaces, Coatings and Films,General Chemistry

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