A paradigm shift in rate determining step from single electron transfer between phenylsulfinylacetic acids and iron(III) polypyridyl complexes to nucleophilic attack of water to the produced sulfoxide radical cation: a non-linear Hammett-Reference-Cited by-同舟云学术

A paradigm shift in rate determining step from single electron transfer between phenylsulfinylacetic acids and iron(III) polypyridyl complexes to nucleophilic attack of water to the produced sulfoxide radical cation: a non-linear Hammett

Published:2016-05-02 Issue:10 Volume:29 Page:496-504
ISSN:0894-3230
Container-title:Journal of Physical Organic Chemistry
language:en
Short-container-title:J. Phys. Org. Chem.

Author:

Subramaniam Perumal¹,Janet Sylvia Jaba Rose Jebamoney²,Jeevi Esther Rathinakumari Rajasingh²

Affiliation:

1. Research Department of Chemistry; Aditanar College of Arts and Science; Tiruchendur 628 216 Tamil Nadu India

2. Department of Chemistry; Nazareth Margoschis College; Nazareth 628 617 Tamil Nadu India

Funder

UGC, SERO, Hyderabad

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

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4. Kinetics and mechanism of oxygenation of aromatic sulfides and arylmercaptoacetic acids by peroxomonophosphoric acid

5. Mechanism of oxygenation of aryl methyl and diaryl sulphoxides by peroxomonophosphoric acid

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