Affiliation:
1. Department of Chemistry Guangdong Provincial Key Laboratory of Catalysis Guangming Advanced Research Institute College of Science Southern University of Science and Technology 1088 Xueyuan Blvd., Nanshan District Shenzhen Guangdong 518055 China
Abstract
AbstractBenefited from the rapid development of MBH reaction, the reaction of MBH adducts have been established as the most synthetically useful transformations. However, compared with the well‐established allylic alkylations and (3+2)‐annulations, the (1+4)‐annulations of MBH adducts have not developed rapidly until recently. As a helpful complement to the (3+2)‐annulations of MBH adducts, the (1+4)‐annulations of MBH adducts opens a robust access to structurally diverse five‐membered carbo‐ and heterocycles. This paper summarizes recent advances in organocatalytic (1+4)‐annulations using MBH adducts as 1 C‐synthons for the construction of functionalized five‐membered carbo‐ and heterocycles.
Funder
National Natural Science Foundation of China
Subject
Materials Chemistry,General Chemical Engineering,Biochemistry,General Chemistry
Cited by
6 articles.
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