N‐Ethynylation of Anilides Decreases the Double‐Bond Character of Amide Bond while Retaining trans ‐Conformation and Planarity
Author:
Affiliation:
1. Showa Pharmaceutical University 3-3165 Higashi-Tamagawagakuen Machida Tokyo 194-8543 Japan
Funder
Japan Science Society
Publisher
Wiley
Subject
General Chemistry,Catalysis,Organic Chemistry
Link
https://onlinelibrary.wiley.com/doi/pdf/10.1002/chem.201901451
Reference60 articles.
1. For recent reviews of twisted amides see:
2. Chemistry of Bridged Lactams and Related Heterocycles
3. Twisted Amides: From Obscurity to Broadly Useful Transition-Metal-Catalyzed Reactions by N−C Amide Bond Activation
4. Pyramidalization/twisting of the amide functional group via remote steric congestion triggered by metal coordination
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