Affiliation:
1. Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials College of Chemistry and Bioengineering Guilin University of Technology Guilin 541004 People's Republic of China
Abstract
AbstractA visible‐light induced cerium‐catalyzed N‐demethylation of N‐methyl amides under air atmosphere to the corresponding of N‐demethylated amides is presented. Upon irradiation the excited states of [CeIVCln]2− are able to activate N‐methyl amides. This reaction provides a methodology to cleave the C−N bond of amides under air conditions.magnified image
Funder
National Natural Science Foundation of China
Natural Science Foundation of Guangxi Province
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