Dynamic Thermoregulatory Textiles Woven from Scalable‐Manufactured Radiative Electrochromic Fibers

Author:

Fan Qingchao1,Fan Hongwei2,Han Haozhi1,Bai Zhiyuan1,Wu Xilu1,Hou Chengyi1,Zhang Qinghong3,Li Yaogang3,Li Kerui1ORCID,Wang Hongzhi1ORCID

Affiliation:

1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and Engineering Donghua University Shanghai 201620 P. R. China

2. Instrumental Analysis & Research Center Shanghai University Shanghai 200444 P. R. China

3. Engineering Research Center of Advanced Glasses Manufacturing Technology Ministry of Education Donghua University Shanghai 201620 P. R. China

Abstract

AbstractTextiles can be promising next‐generation wearable thermal management systems by exhibiting tunable infrared emissivity for dual‐mode control of cooling/warming, yet textiles often exhibit constant infrared emission. Herein, a dynamic thermoregulatory textile is woven from scalable‐manufactured radiative electrochromic fibers and is easily driven by a low voltage in a manner that results in a modulated emissivity of Δɛ≈0.35. Through a synergistic combination of the spiral outer electrode and electrochemically tunable carbon nanotube layer, excellent electrochemical controllability of the fibers is achieved over 100‐m length within 5s because of the decreased internal resistance with increasing length. As a result, the thermoregulatory textile suppresses substantial temperature variation and ensures excellent temperature regulation within ≈1.6 °C for simulated skin (much better than that of traditional textiles: ≈2.9 °C) under an ambient temperature fluctuation of 11.2 °C. Finally, wearable infrared camouflage and invisible infrared displays are also demonstrated by weaving or embroidering the radiative electrochromic fibers onto clothing.

Funder

Science and Technology Commission of Shanghai Municipality

Innovative Research Group Project of the National Natural Science Foundation of China

Publisher

Wiley

Subject

Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials

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