Affiliation:
1. State Key Laboratory of Coordination Chemistry School of Chemistry and Chemical Engineering Collaborative Innovation Center of Advanced Microstructures Nanjing University Nanjing 210023 P. R. China
2. School of Chemical Engineering and Materials Changzhou Institute of Technology Changzhou 213032 P. R. China
3. Department of Orthopedic Surgery Children's Hospital of Nanjing Medical University Nanjing 210000 P. R. China
Abstract
AbstractBitumen, which is widely used in various applications, is facing the challenge of being unsustainable. Many strategies are proposed to recycle or replace bitumen. However, most of them can not address the unsustainability of bitumen from the roots. On the other hand, sulfur exists widely on the earth as a kind of industrial waste despite its extensive applications. Herein, a series of bitumen‐like polymers from elemental sulfur is obtained through an inverse vulcanization reaction. The sulfur‐containing polymers exhibit self‐healing, non‐toxic, and adjustable properties depending on the working environment. Based on these features, the applications of sulfur‐containing polymers in self‐healing waterproof sealants, impact‐resistance or shock‐absorption devices, and non‐Newtonian speed bumps are demonstrated. With the method of synthesizing multifunctional bitumen‐like polymers from sulfur wastes, a feasible way is provided to solve simultaneously the challenging problem of bitumen's unsustainability as well as sulfur's utilization, with the advantages including easy massed‐fabrication, non‐toxicity, extremely low cost (≈2 cents per gram) and environment friendliness.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Jiangsu Province
Subject
Electrochemistry,Condensed Matter Physics,Biomaterials,Electronic, Optical and Magnetic Materials
Cited by
4 articles.
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