Recent Advancements in Ascribing Several Platinum Free Electrocatalysts Pertinent to Hydrogen Evolution from Water Reduction

Author:

Islam Fahamidul12,Ahsan Mohebul13ORCID,Islam Nurnobi1,Hossain Mohammad Imran1ORCID,Bahadur Newaz Mohammed2,Aziz Abdul4,Al‐Humaidi Jehan Y.5ORCID,Rahman Mohammed M.6ORCID,Maiyalagan T.7,Hasnat Mohammad A.18ORCID

Affiliation:

1. Electrochemistry & Catalysis Research Laboratory (ECRL) Department of Chemistry School of Physical Sciences Shahjalal University of Science and Technology Sylhet 3114 Bangladesh

2. Department of Chemistry Faculty of Science Noakhali Science and Technology University Noakhali 3814 Bangladesh

3. Division of Chemistry Department of Science and Humanities Military Institute of Science and Technology, Mirpur Cantonment- 1216 Dhaka Bangladesh

4. Interdisciplinary Research Center for Hydrogen Technologies and Carbon Management (IRC-HTCM) King Fahd University of Petroleum & Minerals KFUPM Box 5040 Dhahran 31261 Saudi Arabia

5. Department of Chemistry College of Science Princess Nourah bint Abdulrahman University P.O. BOX 84428 Riyadh 11671 Saudi Arabia

6. Center of Excellence for Advanced Materials Research (CEAMR) & Chemistry department King Abdulaziz University Jeddah 21589 Saudi Arabia

7. Department of Chemistry SRM Institute of Science and Technology Kattankulathur 603 203 Tamilnadu India

8. International Research Organization for Advanced Science and Technology Kumamoto University 2-39-1 Kurokami, Chuo-ku Kumamoto 860-8555 Japan

Abstract

AbstractThe advancement of a sustainable and scalable catalyst for hydrogen production is crucial for the future of the hydrogen economy. Electrochemical water splitting stands out as a promising pathway for sustainable hydrogen production. However, the development of Pt‐free electrocatalysts that match the energy efficiency of Pt while remaining economical poses a significant challenge. This review addresses this challenge by highlighting latest breakthroughs in Pt‐free catalysts for the hydrogen evolution reaction (HER). Specifically, we delve into the catalytic performance of various transition metal phosphides, metal carbides, metal sulphides, and metal nitrides toward HER. Our discussion emphasizes strategies for enhancing catalytic performance and explores the relationship between structural composition and the performance of different electrocatalysts. Through this comprehensive review, we aim to provide insights into the ongoing efforts to overcome barriers to scalable hydrogen production and pave the way for a sustainable hydrogen economy.

Publisher

Wiley

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