Affiliation:
1. National‐Local Joint Engineering Laboratory for Energy Conservation in Chemical Process Integration and Resources Utilization School of Chemical Engineering and Technology Hebei University of Technology Tianjin 300130 P. R. China
Abstract
AbstractUnidirectional cascade electron transfer induced by multi‐junctions is essential for deep electronic state regulation of the catalytic active sites, while this advanced concept has rarely been investigated in the field of electrocatalysis. In the present work, a dual junction heterostructure (FePc/L‐R/CN) is designed by anchoring iron phthalocyanine (FePc)/MXene (L‐Ti3C2‐R, R═OH or F) heterojunction on g‐C3N4 nanosheet substrates for electrocatalysis. The unidirectional cascade electron transfer (g‐C3N4 → L‐Ti3C2‐R → FePc) induced by the dual junction of FePc/L‐Ti3C2‐R and L‐Ti3C2‐R/g‐C3N4 makes the Fe center electron‐rich and therefore facilitates the adsorption of O2 in the oxygen reduction reaction (ORR). Moreover, the electron transfer between FePc and MXene is facilitated by the axial Fe─O coordination interaction of Fe with the OH in alkalized MXene nanosheets (L‐Ti3C2‐OH). As a result, FePc/L‐OH/CN exhibits an impressive ORR activity with a half‐wave potential (E1/2) of 0.92 V, which is superior over the catalysts with a single junction and the state‐of‐the‐art Pt/C (E1/2 = 0.85 V). This work provides a broad idea for deep regulation of electronic state by the unidirectional cascade multi‐step charge transfer and can be extended to other proton‐coupled electron transfer processes.
Funder
National Natural Science Foundation of China
Natural Science Foundation of Tianjin Municipality
Natural Science Foundation of Hebei Province
Subject
General Physics and Astronomy,General Engineering,Biochemistry, Genetics and Molecular Biology (miscellaneous),General Materials Science,General Chemical Engineering,Medicine (miscellaneous)
Cited by
1 articles.
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