Affiliation:
1. Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
2. School of Advanced Manufacturing Guangdong University of Technology Jieyang 522000 P. R. China
Abstract
AbstractZn powder is considered as a potential Zn metal anode for aqueous Zn‐ion batteries. However, restricted ion/electron transfer and volume effect‐caused electrical contact failure in conventional polymer binder composited Zn powder anodes deteriorate their electrochemical performance. Here, a high‐performance soft solid‐like viscoelastic Zn powder composite anode is proposed based on an oligomer gluing strategy. Benefiting from the viscoelastic properties, the soft‐solid Zn powder composite (ss‐ZnP) anode has significantly enhanced charge transfer, alleviated volume effect, and homogenized interfacial electric field, leading to fast plating/stripping kinetics and dendrite‐free deposition morphology. Furthermore, the assembled NH4V4O10‖ss‐ZnP full cell delivers higher capacity (510 mAh g−1 at 0.1A g−1, 300 mAh g−1 at 1A g−1) and longer lifespan up to 500 cycles at 1 A g−1, superior to conventional polymer binder composited Zn powder anode and other reported rheological Zn powder‐based anodes. Apart from the electrochemical merits, this soft matter‐based design also endows the ss‐ZnP electrode with free‐standing and malleable properties which greatly expand its practical application.
Funder
Guangdong Provincial Pearl River Talents Program
National Natural Science Foundation of China
Subject
General Materials Science,Renewable Energy, Sustainability and the Environment
Cited by
1 articles.
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