Solid‐State Reactions of AgAc with TabHPF 6 at Room Temperature − Isolation and Structural Characterisation of an Unusual Octadecanuclear Silver Thiolate Cluster [Ag 9 (Tab) 8 (MeCN) 8 ] 2 (PF 6 ) 18 ·4MeCN [Tab = 4‐(trimethylammonio)benzenethiolate]

Author:

Chen Jin‐Xiang1,Xu Qing‐Feng1,Xu Ying1,Zhang Yong1,Chen Zhong‐Ning2,Lang Jian‐Ping12

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Engineering, Suzhou University, 1 Shizi Street, Suzhou 215006, Jiangsu, P. R. China, Fax: (internat.) + 86‐512‐65224783

2. State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian, P. R. China

Publisher

Wiley

Subject

Inorganic Chemistry

Reference34 articles.

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2. The structural chemistry of metal thiolate complexes

3. I. Dance K. Fisher G. Lee inMetallothioneins: Synthesis Structure and Properties of Metallothioneins Phytohelatins and Metal‐Thiolate Complexes VCH New York 1992 vol. 13 p. 284−345.

4. Metal Clusters in Chemistry(Eds.: P. Braunstein L. A. Oro P. R. Raithby) Wiley‐VCH New York 1999 vols. 1−3.

5. {Ag5[µ2-S–(CH2)3–NHMe2]3[µ2-S–(CH2)3–NMe2]3}2+, the first thiolate complex of a metal with trigonal bipyramido-M5-trigonal prismo-S6polyhedral stereochemistry

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