Cluster Growth Reactions with Selenido‐Carbonyl Clusters − Synthesis, Characterisation and Theoretical Study of the Dimetallic closo Clusters [WRu 3 (μ 4 ‐Se) 2 (μ‐CO) 4 (CO) 6 (L) 2 ] (L = Phosphane) and of the Donor‐Acceptor Adduct [(CO) 5 W(μ 4 ‐Se)Ru 3 (μ 3 ‐Se)(CO) 7 {P(CH 2 Ph)Ph 2 } 2 ]-Reference-Cited by-同舟云学术

Cluster Growth Reactions with Selenido‐Carbonyl Clusters − Synthesis, Characterisation and Theoretical Study of the Dimetallic closo Clusters [WRu 3 (μ 4 ‐Se) 2 (μ‐CO) 4 (CO) 6 (L) 2 ] (L = Phosphane) and of the Donor‐Acceptor Adduct [(CO) 5 W(μ 4 ‐Se)Ru 3 (μ 3 ‐Se)(CO) 7 {P(CH 2 Ph)Ph 2 } 2 ]

Published:2004-02-24 Issue:5 Volume:2004 Page:1063-1072
ISSN:1434-1948
Container-title:European Journal of Inorganic Chemistry
language:en
Short-container-title:Eur. J. Inorg. Chem.

Author:

Cauzzi Daniele¹,Graiff Claudia¹,Pattacini Roberto¹,Predieri Giovanni¹,Tiripicchio Antonio¹,Kahlal Samia²,Saillard Jean‐Yves²

Affiliation:

1. Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Università di Parma, Parco Area delle Scienze 17/A, 43100 Parma, Italy, Fax: (internat.) + 39‐0521/905‐557

2. LCSIM‐UMR 6511, Institut de Chimie de Rennes, Université de Rennes 1, 35042 Rennes‐Cedex, France

Publisher

Wiley

Subject

Inorganic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejic.200300386

Reference45 articles.

1. D. Cauzzi C. Graiff G. Predieri A. Tiripicchio inMetal Clusters in Chemistry(Eds.: P. Braunstein L. Oro P. Raithby) vol. 1 VCH Weinheim1999 193.

2. Ph3PSe as a convenient synthon for one-step syntheses of Ph3P-substituted selenido carbonyl iron and ruthenium clusters. Crystal structures of Fe3(μ3-Se)(μ-CO)(CO)7(PPh3)2, M3(μ3-Se)2(CO)7(Pph3)2 (MFe or Ru) and Ru4(μ4-Se)2(μ-CO)2(CO)7(PPh3)2

3. Chelating versus bridging behaviour and NMR fluxionality of dppf in the nido clusters [M3Se2(CO)7(dppf )] [M = Fe or Ru, dppf = Fe(η5-C5H4PPh2)2]. Crystal structure of the chelated ruthenium derivative †

4. Reaction of CH2(Ph2PSe)2 with [Ru3(CO)12]. Crystal structure of [Ru4Se4(CO)10(Ph2PCH2PPh2)], a missing link in the [M4E4L12] cubane series (M = Group 8 metal, E = chalcogenido ligand)

5. Multiple oxidative addition of diphenyl-2-thienylphosphine selenide to [Ru3(CO)12]: crystal and molecular structure of [Ru3(μ3-Se)(μ-PPh2)(μ-η1:η2-C4H3S)(CO)6{P(C4H3S)Ph2}]

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