Zinc Chloride‐Treated Indium Sulfide as Buffer Layer for Cd‐Free Antimony Selenide Solar Cells

Author:

Dong Yizhe12,Huang Lei12,Wang Haolin12,Peng Xiaoqi12,Wang Yan12,Tang Rongfeng12,Zhu Changfei12,Chen Tao12ORCID

Affiliation:

1. Hefei National Research Center for Physical Sciences at the Microscale CAS Key Laboratory of Materials for Energy Conversion Department of Materials Science and Engineering School of Chemistry and Materials Science University of Science and Technology of China Hefei 230026 China

2. Institute of Energy Hefei Comprehensive National Science Center Hefei 230051 China

Abstract

In2S3, as a promising environmentally benign semiconductor, is used as a buffer layer in thin‐film solar cells due to its high electron mobility, low toxicity, and excellent thermal and chemical stability. The preparation of a high‐quality In2S3 film is crucial for the improvement of its carrier extraction ability and subsequent deposition of absorber layers. Herein, it is demonstrated for the first time that a posttreatment of In2S3 film with ZnCl2 solution is able to serve as buffer layer for constructing superstrate Sb2Se3 solar cells. The posttreatment with ZnCl2 not only prevents In2S3 from excessive oxidation during annealing process, but also facilitates the growth of (hk1) orientation of Sb2Se3, thereby improving the interfacial contact of In2S3/Sb2Se3. The improved heterojunction quality suppresses the carrier recombination at the interface, and enhances the charge extraction ability of In2S3. As a result, the power conversion efficiency of Sb2Se3 solar cell increases from 2.63% to 5.00%. Herein, a facile and effective strategy is provided for the application of In2S3 as the buffer layer in inorganic chalcogenide solar cells.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Publisher

Wiley

Subject

Electrical and Electronic Engineering,Energy Engineering and Power Technology,Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3