Über den Phosphandiyl-Transfer von invers-polarisierten Phosphaalkenen R1P=C(NMe2)2 (R1 =tBu, Cy, Ph, H) auf Phospheniumkomplexe [(η5-C5H5)(CO)2M=P(R2)R3] (R2 = R3 = Ph; R2 =tBu, R3 = H; R2 = Ph, R3 = N(SiMe3)2)-Reference-Cited by-同舟云学术

Über den Phosphandiyl-Transfer von invers-polarisierten Phosphaalkenen R1P=C(NMe2)2 (R1 =tBu, Cy, Ph, H) auf Phospheniumkomplexe [(η5-C5H5)(CO)2M=P(R2)R3] (R2 = R3 = Ph; R2 =tBu, R3 = H; R2 = Ph, R3 = N(SiMe3)2)

Published:2007-06 Issue:7 Volume:633 Page:994-999
ISSN:0044-2313
Container-title:Zeitschrift für anorganische und allgemeine Chemie
language:de
Short-container-title:Z. anorg. allg. Chem.

Author:

Weber L.,Noveski G.,Stammler H.-G.,Neumann B.

Publisher

Wiley

Subject

Inorganic Chemistry

Reference30 articles.

1. Phosphaalkenes with Inverse Electron Density

2. Reactivity of the Metallophosphaalkene [(η5-C5Me5)(CO)2FeP=C(NMe2)2] towards Alkyl-, Aryl-, Alkenyl-, and Alkynylcarbene Complexes [(CO)5M=C(OEt)R] (M=Cr, W; R=CH3, Ph, CH=CHPh, C≡CPh)

3. Reactivity of the Inversely Polarized Phosphaalkenes RP=C(NMe2)2 (R=tBu, Me3Si, H) towards Arylcarbene Complexes [(CO)5M=C(OEt)Ar] (Ar=Ph, M=Cr, W; Ar=2-MeC6H4, 2-MeOC6H4, M=W)

4. Reactivity of the Inversely Polarized Phosphaalkene HPC(NMe2)2 Toward Carbene Tungsten Complexes [(CO)5WC(R1)OR2] (R1 = c-C3H5, c-C5H9; R2 = Me, Et, Me3Si): A Novel Access to η1-Phosphaalkene Complexes [(CO)5W−P(R2)C(H)NMe2]

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