Affiliation:
1. Institute of Applied Materials Science, Vietnam Academy of Science and Technology 1B TL29, Thach Loc Ward, District 12 Ho Chi Minh City 70000 Viet Nam
2. Graduate University of Science and Technology, Vietnam Academy of Science and Technology 18 Hoang Quoc Viet Cau Giay Hanoi 10072 Viet Nam
3. Research Institute of Forest Industry Vietnamese Academy of Forest Sciences Duc Thang Bac Tu Liem District Hanoi 10000 Viet Nam
Abstract
AbstractComposite nanomaterials of ZnO/chitosan oligosaccharide (ZnO/COS) and ZnO/chitosan oligosaccharide iodine (ZnO/CTS‐I2) were expected to have effective antimicrobial effects due to the synergistic effects of the components. In this work, we present a method to synthesize ZnO nanoparticles with size of 12.3‐15.0 nm stabled in COS with low molecular weight (Mw) 3,321 g/mol and COS‐I2 complex by precipitation of Zn2+ with NaOH at pH 9, and then ultrasonic treatment to form ZnO nanoparticles. The UV‐Vis spectra of ZnO/COS and ZnO/COS‐I2 composite nanomaterials both appeared absorption peaks typical for surface plasmon resonances of ZnO nanoparticles in solution at 372 and 370 nm, respectively. X‐ray diffraction (XRD) patterns confirmed the formation of ZnO/COS‐I2 with wurtzite crystal structure characterized in both materials. The FT‐IR spectra of COS, COS‐I2, nano ZnO/COS, and nano ZnO/COS‐I2 were measured. The characteristic peaks for the bonding vibrations of –OH and –NH2 groups of ZnO/COS and ZnO/COS‐I2 shifted to a larger wavenumber than that of COS. The prepared ZnO/COS and ZnO/COS‐I2 nanocomposite materials may have potential for application as antibacterial agents used in medicine, food, and agricultural product preservation, control of harmful microorganisms on plants, and plant growth promotion.