Affiliation:
1. State Key Laboratory and Institute of Elemento-Organic Chemistry Frontiers Science Center for New Organic Matter College of Chemistry Nankai University 94 Weijin Road Tianjin 300071 China
Abstract
AbstractElectrochemistry utilizes electrons as a potent, controllable, and traceless alternative to chemical oxidants or reductants, and typically offers a more sustainable option for achieving selective organic synthesis. Recently, the merger of electrochemistry with readily available electrophiles has been recognized as a viable and increasingly popular methodology for efficiently constructing challenging C−C and C‐heteroatom bonds in a sustainable manner for complex organic molecules. In this mini‐review, we have systematically summarized the most recent advances in electroreductive cross‐electrophile coupling (eXEC) reactions during the last decade. Our focus has been on readily available electrophiles, including aryl and alkyl organic (pseudo)halides, as well as small molecules such as CO2, SO2, and D2O.
Funder
National Key Research and Development Program of China
Fundamental Research Funds for the Central Universities
National Natural Science Foundation of China
Subject
General Chemistry,Catalysis
Cited by
19 articles.
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