Predictable Selectivity in Remote C−H Oxidation of Steroids: Analysis of Substrate Binding Mode-Reference-Cited by-同舟云学术

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Predictable Selectivity in Remote C−H Oxidation of Steroids: Analysis of Substrate Binding Mode

Published:2020-05-20 Issue:31 Volume:59 Page:12703-12708
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew. Chem. Int. Ed.

Author:

Olivo Giorgio¹,Capocasa Giorgio²,Ticconi Barbara²,Lanzalunga Osvaldo²,Di Stefano Stefano²,Costas Miquel¹^ORCID

Affiliation:

1. Institut de Química Computacional i Catàlisi (IQCC) and Departament de Química Universitat de Girona Campus de Montilivi, C/ Pic de Peguera 15 17003 Girona Spain

2. Dipartimento di Chimica and Istituto CNR per i Sistemi Biologici (ISB-CNR) Sezione Meccanismi di Reazione Sapienza Università di Roma P. le A. Moro 5 00185 Rome Italy

Funder

Ministerio de Economía y Competitividad

Generalitat de Catalunya

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202003078

Reference61 articles.

1. The Structural Basis for Substrate Anchoring, Active Site Selectivity, and Product Formation by P450 PikC from Streptomyces venezuelae

2. Selective oxidation of carbolide C-H bonds by an engineered macrolide P450 mono-oxygenase

3. Enzymatic hydroxylation of an unactivated methylene C–H bond guided by molecular dynamics simulations

4. The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

5. Innate and Guided C–H Functionalization Logic

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4. Proximity Effects on the Reactivity of a Nonheme Iron (IV) Oxo Complex in C−H Oxidation;Angewandte Chemie;2024-04-03

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