Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation-Reference-Cited by-同舟云学术

Boron‐Centered Lewis Superacid through Redox‐Active Ligands: Application in C−F and S−F Bond Activation

Published:2023-02-09 Issue:13 Volume:62 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Köring Laura¹,Stepen Arne¹,Birenheide Bernhard²,Barth Simon²,Leskov Maxim²,Schoch Roland¹,Krämer Felix²,Breher Frank²^ORCID,Paradies Jan¹^ORCID

Affiliation:

1. Department of Chemistry Paderborn University Warburger Strasse 100 33098 Paderborn Germany

2. Institute of Inorganic Chemistry Karlsruhe Institute of Technology (KIT) Engesserstr. 15 76131 Karlsruhe Germany

Abstract

AbstractA series of redox‐responsive ferrocenyl‐substituted boranes and boronic esters were synthesized. Oxidation of the ferrocenyl ligand to the ferrocenium resulted in a drastic increase in the Lewis acidity beyond the strength of SbF5, which was investigated experimentally and computationally. The resulting highly Lewis acidic boron compounds were used for catalytic C−F and S−F bond activation.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202216959

Reference112 articles.

2. Diverse Uses of the Reaction of Frustrated Lewis Pair (FLP) with Hydrogen

3. FLP catalysis: main group hydrogenations of organic unsaturated substrates

4. Frustrated Lewis Pair Chemistry: Development and Perspectives

5. Chemie frustrierter Lewis-Paare: Entwicklung und Perspektiven

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