A review on electrocatalytic CO2 conversion via C–C and C–N coupling

Author:

Zhang Zhuangzhi1,Li Sijun2,Zhang Zheng3,Chen Zhou4,Wang Hua2,Meng Xianguang15ORCID,Cui Wenquan56,Qi Xiwei57,Wang Jiacheng89

Affiliation:

1. Hebei Provincial Laboratory of Inorganic Nonmetallic Materials, College of Materials Science and Engineering North China University of Science and Technology Tangshan China

2. Key Laboratory of Luminescence Analysis and Molecular Sensing, Ministry of Education, College of Chemistry and Chemical Engineering Southwest University Chongqing China

3. State Key Laboratory of New Textile Materials and Advanced Processing Technologies, Hubei Key Laboratory of Biomass Fibers and Eco‐Dyeing and Finishing, College of Chemistry and Chemical Engineering Wuhan Textile University Wuhan China

4. College of Materials Xiamen University Xiamen China

5. Hebei Iron and Steel Laboratory Tangshan China

6. Hebei Key Laboratory for Environment Photocatalytic and Electrocatalytic Materials, College of Chemical Engineering North China University of Science and Technology Tangshan China

7. College of Metallurgy and Energy North China University of Science and Technology Tangshan China

8. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics Chinese Academy of Sciences Shanghai China

9. Institute of Electrochemistry, School of Materials Science and Engineering Taizhou University Taizhou China

Abstract

AbstractElectrochemical C–C and C–N coupling reactions with the conversion of abundant and inexpensive small molecules, such as CO2 and nitrogen‐containing species, are considered a promising route for increasing the value of CO2 reduction products. The development of high‐performance catalysts is the key to the both electrocatalytic reactions. In this review, we present a systematic summary of the reaction systems for electrocatalytic CO2 reduction, along with the coupling mechanisms of C–C and C–N bonds over outstanding electrocatalytic materials recently developed. The key intermediate species and reaction pathways related to the coupling as well as the catalyst‐structure relationship will be also discussed, aiming to provide insights and guidance for designing efficient CO2 reduction systems.

Funder

National Natural Science Foundation of China

Publisher

Wiley

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