Characterization and Superhydrophobic Anticorrosive Coating of AA-7475/ZrO2/Polymer Nanocomposites

Abstract

An AA-7475 is coated with superhydrophobic (SH) polymer nanocomposites (PNCs), emphasizing the coating’s manufacturing, characterization, and anticorrosive qualities. Coating AA-7475 alloy with polyvinyl chloride (PVC), copper stearate (CS), and zirconium oxide (ZrO2) nanoparticles produces the desired superhydrophobic. Using an X-ray diffractometer, field-emission scanning electron microscopy, Fourier-transform infrared spectrometer, ZrO2 nanoparticles, CS, and PVC PNCs are analyzed structurally and molecularly. The atomic force microscope picture was analyzed to determine how the surface roughness affected the SH behavior reached by changing the weight percentage of ZrO2 nanoparticles from 0.6 to 3.0 wt%. PNC-5 with 3.0 wt% ZrO2 nanoparticles is used as resistance to corrosion coating for AA-7475 due to its water contact angle of 154°. In a 3.5% NaCl solution, uncoated and PNC-5-coated AA-7475 are examined using potentiodynamic polarization and electrochemical spectroscopy. PNC-5 coating reduces AA-7475 corrosion rate from 23.75 to 0.2253 mpy. In this study, we use polarization resistance, corrosion resistance efficiency, double layer capacitance, corrosion current density, and charge transfer resistance to demonstrate that the SH surface air trapping phenomena are responsible for effective corrosion resistance.