Highly Efficient Selective Oxygenation of Sulfides to Sulfoxides by Oxalic Acid Dihydrate in the Presence of H2O2-Reference-Cited by-同舟云学术

Highly Efficient Selective Oxygenation of Sulfides to Sulfoxides by Oxalic Acid Dihydrate in the Presence of H2O2

Published:2012 Issue:2 Volume:9 Page:863-868
ISSN:0973-4945
Container-title:E-Journal of Chemistry
language:en
Short-container-title:E-Journal of Chemistry

Author:

Mokhtary Masoud¹,Qandalee Mohammad²,Niaki Masoumeh Rastegar³

Affiliation:

1. Department of Chemistry, Rasht Branch, Islamic Azad University, Rasht, Iran

2. Department of Biology, Garmsar Branch, Islamic Azad University, Garmsar, Iran

3. Department of Chemistry, Science and Research, Amol Branch, Islamic Azad University, Amol, Iran

Abstract

A highly efficient method for the oxidation of sulfides to sulfoxides using oxalic acid dihydrate in the presence of hydrogen peroxide has been developed. A versatile procedure for the oxidation of sulfides to sulfoxides without any over-oxidation to sulfones has been reported. This procedure cleanly oxidizes sulfides to the corresponding sulfoxides in excellent yields at ambient temperature.

Funder

Islamic Azad University

Publisher

Hindawi Limited

Subject

General Chemistry

Link

http://downloads.hindawi.com/journals/jchem/2012/412798.pdf

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