The IR Spectra, Molar Absorptivity, and Integrated Molar Absorptivity of the C76-D2and C84-D2:22 Isomers

Author:

Jovanović Tamara1ORCID,Koruga Đuro1,Jovančićević Branimir2

Affiliation:

1. Department of Biomedical Engineering, Faculty of Mechanical Engineering, University of Belgrade, Kraljice Marije 16, 11120 Belgrade, Serbia

2. Department of Applied Chemistry, Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, 11000 Belgrade, Serbia

Abstract

The FT-IR spectra of the stable C76and C84isomers of D2symmetry, isolated by the new, advanced extraction and chromatographic methods and processes, were recorded by the KBr technique, over the relevant region from 400 to 2000 cm−1, at room temperature. All the observed infrared bands are in excellent agreement with the semiempirical QCFF/PI, DFT, and TB potential calculations for these fullerenes, which is presented in this article, as the evidence of their validity. The molar absorptivityεand the integrated molar absorptivityψof their IR absorption bands were determined and reported together with the relative intensities. Excellent agreement is found between the relative intensities of the main and characteristic absorption maxima calculated fromελand from theψλvalues in adequate integration ranges. These results are significant for the identification and quantitative determination of the C76-D2and C84-D2:22 fullerenes, either in natural resources on Earth and in space or in artificially synthesized and biomaterials, electronic, optical, and biomedical devices, sensors, polymers, optical limiters, solar cells, organic field effect transistors, special lenses, diagnostic and therapeutic agents, pharmaceutical substances in biomedical engineering, and so forth.

Funder

Ministarstvo Prosvete, Nauke i Tehnološkog Razvoja

Publisher

Hindawi Limited

Subject

General Materials Science

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