A Novel Approach to Improve the Barrier Properties of PET/Clay Nanocomposites

Abstract

An investigation of oleic acid-modified clay versus plain clay with regard to the physical and barrier properties of PET/clay nanocomposites was performed. Montmorillonite (MMT) and Cloisite 30B nanoclays were modified by long-chain oleic acid and identified as ol-MMT and ol-30B, respectively. Fourier Transformed Infrared Spectroscopy and X-ray diffraction (XRD) results revealed that the fatty acid was associated with the clay surface and that the gallery spacing of the layered silicates was expanded. In the case of ol-MMT, a disordered structure of layered silicates was achieved. TGA results indicated that ol-MMT showed thermal stability and could survive PET processing temperature. The degradation of ol-30B, however, increased after modification because of the presence of oleic acid. PET/clay nanocomposites were prepared with modified ol-MMT and modified ol-30B by using a twin screw extruder. XRD indicated that there was a significant improvement on the dispersion of nanoclays modified with long-chain oleic acid into the PET matrix, and an exfoliated structure was achieved. DSC data also revealed that crystallization behaviors of nanocomposites prepared with oleic acid-modified clays are similar to that of extruded PET. Significant improvements in the mechanical and barrier properties of stretched PET/clay nanocomposites were also achieved.