Adsorption of Phenol onto Aluminum Oxide Nanoparticles: Performance Evaluation, Mechanism Exploration, and Principal Component Analysis (PCA) of Thermodynamics

Abstract

The removal of phenolic compounds from aqueous solutions using novel adsorption techniques becomes a key research item. Of those, nanoparticles in particular, the low-cost and the high-strength aluminum oxide nanoparticles showed promising results in pollutant uptake and increase in the adsorption efficiency. This study examined various physicochemical process parameters such as temperature, pH, initial phenol concentration, and adsorbent doses, in addition to the impact of those parameters on the adsorption removal mechanism of phenol. The results highlighted that aluminum oxide nanoparticles successfully exhibited superior phenol removal from an aqueous solution in addition to a high potential regeneration of the consumed nanoparticles by HCl. For the adsorbent mass of 0.5 g, phenol adsorption uptake reached 92%. Kinetic studies performed using several models demonstrated the data best fitting with a pseudo-second-order kinetic model. Examining equilibrium studies of various isotherms, the adsorption data of phenol into aluminum oxide nanoparticles was confirmed to be controlled by film diffusion and best represented by the Langmuir isotherm. The maximum capacity of adsorption was 16.97 mg/g. For thermodynamics studies, the results indicated that the adsorption process can vary between endothermic and exothermic reactions. Such relative differences in heat generation and spontaneity in adsorption processes were demonstrated and confirmed by principal component analysis (PCA). This evidence is key for future investigations for the efficiency of adsorption conditions concerning the contaminant type and adsorbate compounds.