Affiliation:
1. Department of Chemistry, University of North Dakota, Grand Forks, ND 58202-9024, United States
Abstract
This review covers recent approaches to the synthesis of tertiary phosphines through the C–
PR<sub>2</sub> (R = alkyl or aryl) bond formation reactions using palladium. The methods include Pd-catalyzed
additions of HPR2 to double and triple bonds, substitution and dynamic kinetic resolution of diaryl
(pseudo) halide compounds, reactions of cyclopalladated complexes with MPR<sub>2</sub> (M = Li or K) or HPR<sub>2</sub>,
intramolecular phosphination, and C–P<sup>+</sup> bond cleavages. Together these methods allow for the preparation
of diversely functionalized achiral or enantiopure tertiary phosphines for use in organo- and transition
metal catalysis among other important applications.
Publisher
Bentham Science Publishers Ltd.
Cited by
3 articles.
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