Effect of Gel on the Green Strength of Natural Rubber

Author:

Kawahara Seiichi1,Isono Yoshinobu1,Sakdapipanich Jitladda T.2,Tanaka Yasuyuki2,Aik-Hwee Eng3

Affiliation:

1. 1Faculty of Engineering, Nagaoka University of Technology Nagaoka, Niigata 940-2188, Japan; email:kawahara@chem.nagaokaut.ac.jp

2. 2Department of Chemistry, Faculty of Science, Mahidol University Rama VI Road, Bangkok 10400, Thailand

3. 3Technology and Engineering Division, Malaysian Rubber Board 260, Jalan Ampang, 50450 Kuala Lumpur, Malaysia

Abstract

Abstract The outstanding properties of natural rubber, e.g., green strength and rapid crystallization, were attributed to the chemical branching that formed at both chain ends of the rubber molecule during the preservation of the latex in the presence of ammonia. The gel content of natural rubbers from various clonal origins increased during the preservation, but decreased after deproteinization of the aged latex. The crystallization of acetone-extracted rubber was slightly suppressed as the gel content increased. The increase in green strength during the preservation was studied in connection with the gel content and degree of branching of the rubber.

Publisher

Rubber Division, ACS

Subject

Materials Chemistry,Polymers and Plastics

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