Abstract
AbstractIn this article, a newly discovered nanostructure, that is, island‐nanomatrix structure, of natural rubber is introduced after reviewing previous studies on the structure of natural rubber. The reason why the structures of ω‐ and α‐terminal groups of natural rubber have not been elucidated, yet, is described in relation to the island‐nanomatrix structure. In addition, the effects of the proteins and phospholipids that are constituents of the island‐nanomatrix structure on mechanical properties, degradation, crystallinity, and vulcanization of natural rubber are comprehensively described by comparing them with those reported in the literatures. Furthermore, the structures ofcis‐1,4‐polyisoprenes obtained from various plants and natural rubber prepared by various manufacturing processes are discussed in relation to their mechanical properties.
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