Preparation and Characterization of Crystalline 3,4-Polyisoprene-Reference-Cited by-同舟云学术

Preparation and Characterization of Crystalline 3,4-Polyisoprene

Published:1994-11-01 Issue:5 Volume:67 Page:865-870
ISSN:1943-4804
Container-title:Rubber Chemistry and Technology
language:en
Short-container-title:

Author:

Hsu W. L.¹,Halasa A. F.¹

Affiliation:

1. 1Tire Materials & Compound Research, Corporate Research, The Goodyear Tire & Rubber Co., 142 Goodyear Blvd., Akron, OH 44305

Abstract

Abstract Gel-free, semi-crystalline polyisoprenes containing 70–81% 3,4 units were prepared using an improved iron catalyst. A partially hydrolyzed triisobutylaluminum was used as the reducing agent for the improved catalyst, which allowed the title polymers to be prepared in aliphatic solvents at fast rates.

Publisher

Rubber Division, ACS

Subject

Materials Chemistry,Polymers and Plastics

Link

http://meridian.allenpress.com/rct/article-pdf/67/5/865/1944682/1_3538717.pdf

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