Author:
Redwood M. E.,Willis C. J.
Abstract
The preparation is described of the trifluoromethoxides of the heavier alkali metals, i.e. MOCF3 where M = K, Rb, or Cs. These are stable, crystalline, ionic solids made by the reversible reaction of carbonyl fluoride with the appropriate metal fluoride. No trifluoromethoxides could be prepared from lithium, sodium, barium, or thallium(I) fluorides. Factors affecting the relative stability of such compounds are discussed.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
123 articles.
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