Author:
Platford R. F.,Spinks J. W. T.
Abstract
Air-saturated aqueous chloral hydrate has been irradiated with beta rays and the acid yield as determined by titration has been studied as a function of dose rate, temperature, and initial concentration of the chloral hydrate.The average lifetime of the intermediates has been found, by means of the rotating sector technique, to be about 0.5 second. Propagation and termination rate constants for the reaction have been calculated and an effort has been made to explain the results observed in terms of a free radical chain reaction.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
14 articles.
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