IRRADIATION OF AQUEOUS CHLORAL HYDRATE SOLUTIONS WITH Co60 GAMMA-RAYS: AVERAGE LIFETIME OF THE FREE RADICAL CHAINS

Author:

Freeman G. R.,Cleave A. B. Van,Spinks J. W. T.

Abstract

When aqueous one molar chloral hydrate solutions are irradiated with X rays or gamma-rays, hydrochloric acid is produced. The reaction appears to be a chain reaction. The average free radical chain lifetime, as determined using a rotating sector, is approximately 0.1 sec.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Cited by 18 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. The Application of Radiation Chemistry to Mechanistic Studies in Organic Chemistry;Progress in Physical Organic Chemistry;2007-04-04

2. Radiation-induced condensation of formaldehyde and urea;International Journal of Radiation Applications and Instrumentation. Part C. Radiation Physics and Chemistry;1991-01

3. Chemistry of chloral;Chemical Reviews;1975-06-01

4. Chloral Hydrate;Analytical Profiles of Drug Substances;1973

5. An analytical method for determining rate constants using a periodical irradiation technique;Canadian Journal of Chemistry;1969-12-15

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