An analytical method for determining rate constants using a periodical irradiation technique

Abstract

A new analytical method is presented for the determination of rate constants using a periodical irradiation technique. This method is applicable to reactions which have both a first and a second order termination for the chain radical concentration, and is illustrated for the radiolysis of aqueous solutions of chloral hydrate by 137Cs γ rays. The apparent rate constant of first order termination, and the mean chain life time of the chain radical were determined to be 1.10 s−1, and 0.25 s for 400 rad/min, at 22 °C, respectively.