Synthesis, structural characterization, and reactivity of Cp*Ru(N-phosphinoamidinate) complexes-Reference-Cited by-同舟云学术

Synthesis, structural characterization, and reactivity of Cp*Ru(N-phosphinoamidinate) complexes

Published:2014-03 Issue:3 Volume:92 Page:194-200
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Kelly Colin M.¹,Ruddy Adam J.¹,Wheaton Craig A.¹,Sydora Orson L.²,Small Brooke L.²,Stradiotto Mark¹,Turculet Laura¹

Affiliation:

1. Department of Chemistry, Dalhousie University, 6274 Coburg Road, P.O. Box 15000, Halifax, NS B3H 4R2, Canada.

2. Research and Technology, Chevron Phillips Chemical Company, 1862 Kingwood Drive, Kingwood, TX 77339, USA.

Abstract

We report herein on the synthesis and spectroscopic/crystallographic characterization of the first isolable, formally 16-electron Cp*Ru(κ2-P∼N) species, which are supported by N-phosphinoamidinate ligands. Despite the stability of such complexes, they have been shown to readily coordinate two-electron (L) donors including carbon monoxide and 2,6-xylylisocyanide, affording crystallographically characterized 18-electron Cp*Ru(L)(κ2-P∼N) adducts. Preliminary reactivity studies confirm that such complexes are capable of extruding hydrogen from ammonia borane.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/cjc-2013-0474

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