Synthetic investigations of low-coordinate (N-phosphino-amidinate) nickel chemistry: agostic alkyl complexes and benzene insertion into Ni

Synthetic investigations of low-coordinate (N-phosphino-amidinate) nickel chemistry: agostic alkyl complexes and benzene insertion into Ni–H

Published:2020 Issue:15 Volume:49 Page:4811-4816
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Macaulay Casper M.¹²³⁴,Samolia Madhu⁵⁶⁷⁸,Ferguson Michael J.⁹¹¹⁰¹¹⁴^ORCID,Sydora Orson L.¹²¹³¹⁴¹⁵⁸^ORCID,Ess Daniel H.⁵⁶⁷⁸^ORCID,Stradiotto Mark¹²³⁴^ORCID,Turculet Laura¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Dalhousie University

3. Halifax

4. Canada

5. Department of Chemistry and Biochemistry

6. Brigham Young University

7. Provo

8. USA

9. X-Ray Crystallography Laboratory

10. University of Alberta

11. Edmonton

12. Research and Technology

13. Chevron Phillips Chemical Company LP

14. 1862 Kingwood Drive

15. Kingwood

Abstract

The first product arising from benzene insertion into Ni–H, and the first heterobidentate β- or γ-agostic nickel-alkyl complexes, are reported.

Funder

Natural Sciences and Engineering Research Council of Canada

Dalhousie University

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00527D

Reference32 articles.

1. Nickel Hydride Complexes

2. Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

3. Walking Metals for Remote Functionalization

4. Alkene Isomerization–Hydroboration Catalyzed by First-Row Transition-Metal (Mn, Fe, Co, and Ni) N-Phosphinoamidinate Complexes: Origin of Reactivity and Selectivity

5. A comparative analysis of hydrosilative amide reduction catalyzed by first-row transition metal (Mn, Fe, Co, and Ni) N-phosphinoamidinate complexes

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Redox–Transmetalation Reactions: Easy Access to Homo- and Heterodimetallic d⁸,d¹⁰ Complexes;Inorganic Chemistry;2023-11-21

2. Mechanism of 8-Aminoquinoline-Directed Ni-Catalyzed C(sp3)–H Functionalization: Paramagnetic Ni(II) Species and the Deleterious Effect of Carbonate as a Base;Organometallics;2021-05-26