Author:
Allen. A. D.,Barrett P. F.
Abstract
The kinetics in diglyme are reported for the two reactions of [Et4N][M(CO)5X] with aryl phosphines to form cis-[Et4N][PR3M(CO)4X] and PR3M(CO)5 where M = Cr, Mo, or W, X = Cl, Br, or I, and [Formula: see text] (p-FC6H4)3P, or (p-ClC6H4)3P. The reactions of cis-[Et4N][PR3M(CO)4X] with excess phos-phine to form (PR3)2M(CO)4 have also been studied kinetically. Possible mechanisms for these three types of reactions are discussed.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
24 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Carbon Monoxide-Releasing Molecules;Advances in Bioorganometallic Chemistry;2019
2. Kinetic studies of thermal dissociation of carbon monoxide ligands from manganese tri- and tetra-carbonyl derivatives containing the bulky dipiperidylmethane ligand, CH2Pip2;Inorganica Chimica Acta;2019-01
3. Diversity and design of metal-based carbon monoxide-releasing molecules (CO-RMs) in aqueous systems: revealing the essential trends;Dalton Transactions;2009
4. Stability and Bonding Situation of Electron-Deficient Transition-Metal Complexes. Theoretical Study of the CO-Labilizing Effect of Ligands L in [W(CO)5L] (L = C2H2, NCH, N2, C2H4, OH2, SH2, NH3, F-, Cl-, OH-, SH-) and [W(CO)4L]2- (L2- = O2C2H22-, S2C2H22-) and the Structure of the 16-Valence-Electron Complexes [W(CO)4L] and [W(CO)3L]2-;Organometallics;2001-05-17
5. Theoretical Study of the Electronic Structure of Group 6 [M(CO)5X]- Species (X = NH2, OH, Halide, H, CH3) and a Reinvestigation of the Role of π-Donation in CO Lability;Inorganic Chemistry;1999-10-01