Stability and Bonding Situation of Electron-Deficient Transition-Metal Complexes. Theoretical Study of the CO-Labilizing Effect of Ligands L in [W(CO)5L] (L = C2H2, NCH, N2, C2H4, OH2, SH2, NH3, F-, Cl-, OH-, SH-) and [W(CO)4L]2- (L2- = O2C2H22-, S2C2H22-) and the Structure of the 16-Valence-Electron Complexes [W(CO)4L] and [W(CO)3L]2--Reference-Cited by-同舟云学术

Stability and Bonding Situation of Electron-Deficient Transition-Metal Complexes. Theoretical Study of the CO-Labilizing Effect of Ligands L in [W(CO)5L] (L = C2H2, NCH, N2, C2H4, OH2, SH2, NH3, F-, Cl-, OH-, SH-) and [W(CO)4L]2- (L2- = O2C2H22-, S2C2H22-) and the Structure of the 16-Valence-Electron Complexes [W(CO)4L] and [W(CO)3L]2-

Published:2001-05-17 Issue:12 Volume:20 Page:2510-2524
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Kovacs Attila¹,Frenking Gernot¹

Affiliation:

1. Research Group for Technical Analytical Chemistry of the Hungarian Academy of Sciences at the Institute of General and Analytical Chemistry, Technical University of Budapest, Szt. Gellért tér 4, H-1521 Budapest, Hungary, and Fachbereich Chemie, Philipps-Universität, Hans-Meerwein-Strasse, D-35032 Marburg, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om0101893

Reference55 articles.

1. Chemical bonding in hypervalent molecules. The dominance of ionic bonding and negative hyperconjugation over d-orbital participation

2. Hypercoordinate molecules of second-row elements: d functions or d orbitals?

3. Rigorous interpretation of electronic wave functions. 2. Electronic structures of selected phosphorus, sulfur, and chlorine fluorides and oxides

4. Chemical Bonding to Hypercoordinate Second-Row Atoms: d Orbital Participation versus Democracy

5. Characterization of Electronic Structure in Molecules by One-Center Expansion Techniques. No Three-Center Four-Electron Bond in PF5

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