CuSO4·5H2O-catalyzed alkynylphosphonates formation — An efficient coupling reaction of terminal alkynes with H-phosphonates-Reference-Cited by-同舟云学术

CuSO4·5H2O-catalyzed alkynylphosphonates formation — An efficient coupling reaction of terminal alkynes with H-phosphonates

Published:2012-09 Issue:9 Volume:90 Page:747-752
ISSN:0008-4042
Container-title:Canadian Journal of Chemistry
language:en
Short-container-title:Can. J. Chem.

Author:

Qu Zhibo¹,Chen Xiaolan¹,Yuan Jinwei²,Qu Lingbo¹²,Li Xu¹,Wang Fujun¹,Ding Xiling¹,Zhao Yufen¹³

Affiliation:

1. Department of Chemistry, Zhengzhou University, Key Laboratory of Chemistry Biology and Organic Chemistry, Zhengzhou 450052, P.R. China.

2. School of Chemistry & Chemical Engineering, Henan University of Technology, Zhengzhou 450001, P.R. China.

3. Department of Chemistry, Xiamen University, Xiamen 361005, P.R. China.

Abstract

It was recently discovered that easily available CuSO4·5H2O could be employed as an efficient catalyst towards the coupling reactions of terminal alkynes with H-phosphonates, which finally led to the formation of a large variety of novel alkynylphosphates.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

Link

http://www.nrcresearchpress.com/doi/pdf/10.1139/v2012-029

Reference48 articles.

1. Retro-Diels−Alder Reaction: Possible Involvement in the Metabolic Activation of 7-Oxabicyclo[2.2.1]hepta-2(3),5(6)-diene-2,3-dicarboxylates and a Phosphonate Analog

2. Isopolar Phosphonate Analogue of Adenosine Diphosphate Ribose

3. Diethyl 3-iodopropynylphosphonate: an alkylative .beta.-keto phosphonate equivalent

4. Enantioselective total synthesis of a protosterol, 3.beta.,20-dihydroxyprotost-24-ene

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