Ruthenium-Catalyzed [2+2+2] Bis-Homo-Diels–Alder Cycloadditions of 1,5-Cyclooctadiene with Alkynyl Phosphonates

Author:

Petko Dina,Pounder Austin,Tam William1

Affiliation:

1. Guelph-Waterloo Centre for Graduate Work in Chemistry and Biochemistry, Department of Chemistry, University of Guelph

Abstract

The ruthenium-catalyzed [2+2+2] bis-homo-Diels–Alder cycloaddition between 1,5-cyclooctadiene and alkynyl phosphonates was investigated. Various alkynyl phosphonate moieties were found to be compatible with the cycloaddition to give the tricyclo[4.2.2.02,5]dec-7-ene tricyclic compounds in yields of 46–97%.

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

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