Author:
Cornelissen Carsten,Chan Gigi,Masuda Jason D,Stephan Douglas W
Abstract
The pentafluoroaryl amine (C6F5)2NH (1) reacts with AlH3·NEtMe2 to give [(C6F5)2N]AlH2·NEtMe2 (2) and [(C6F5)2N]2AlH·NEtMe2 (3). The related fluorinated-aryl amine (C6F5)(n-C4H9)NH (4) also reacts with AlH3·NEtMe2 to give [(C6F5)(n-C4H9)N]3Al·NEtMe2 (5). This latter compound undergoes ligand exchange with PMe3 or N-methylimidazole to form [(C6F5)(n-C4H9)N]3Al·PMe3 (6) and [(C6F5)(n-C4H9)N]3Al·(Me-imid) (7), respectively. The latter amine also reacts with AlMe3, affording [Me2AlN(C6F5)(n-C4H9)]2 (8).Key words: almunium, amides, pentafluorophenylamine.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
10 articles.
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