Author:
Tanner Dennis D.,Wada Naoto,Brownlee Brian G.
Abstract
The substitution reactions of pentachlorobenzenesulfenyl chloride with saturated alkanes were found to proceed by a free radical chain mechanism where the pentachlorobenzenethiyl radical is the predominant chain-carrying species. The selectivity of this radical could be determined by the investigation of the photoinitiated reactions of bispentachlorophenyl disulfide with a number of alkanes.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
14 articles.
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