Kinetics of sulfur-transfer from titanocene (poly)sulfides to sulfenyl chlorides: rapid metal-assisted concerted substitution-Reference-Cited by-同舟云学术

Kinetics of sulfur-transfer from titanocene (poly)sulfides to sulfenyl chlorides: rapid metal-assisted concerted substitution

Published:2024 Issue:30 Volume:15 Page:11875-11883
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Helou de Oliveira Pedro H.¹,Boaler Patrick J.¹,Hua Guoxiong²,West Nathan M.³,Hembre Robert T.³,Penney Jonathan M.⁴,Al-Afyouni Malik H.⁴,Woollins J. Derek⁵,García-Domínguez Andrés¹,Lloyd-Jones Guy C.¹^ORCID

Affiliation:

1. School of Chemistry, University of Edinburgh, David Brewster Road, Edinburgh, EH9 3FJ, UK

2. School of Chemistry, University of St Andrews, North Haugh, St Andrews, KY16 9ST, UK

3. Eastman Chemical Company, 200 S Wilcox Dr, Kingsport, Tennessee 37660, USA

4. Flexsys America L.P., 260 Springside Drive, Akron, OH 44333, USA

5. Department of Chemistry, Khalifa University, Abu Dhabi, UAE

Abstract

The mechanism has been investigated by stopped-flow UV-Vis/NMR, titrations, numerical kinetic modelling and KS-DFT calculations.

Funder

Royal Society

Eastman Chemical Company

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02737J

Reference78 articles.

1. Cyclometallapolysulfanes (and Selanes) of Bis(η5-Cyclopentadienyl) Titanium(IV), Zirconium(IV), Molybdenum(IV), and Tungsten(IV)

2. Di‐π‐cyclopentadienyl‐titan(IV)‐pentaselenid und ‐pentasulfid, zwei Hetero‐cyclohexachalkogene in fixierter Konformation

3. Metallorganische Polychalkogenid‐Chelate, I. Bildung von Titana‐cyclohexaschwefel aus Polysulfiden

4. Catenated polysulfur ligands: the pentasulfides of di-η5-cyclopentadienyl-zirconium(IV) and -hafnium(IV)