(para-Diphenylphosphino)benzenesulfonic acid and its ruthenium(II) complexes: an old water soluble phosphine ligand in a new perspective

Abstract

Chloro- and hydrido-complexes of ruthenium(II) with potassium (4-diphenylphosphino)benzenesulfonate (pTPPMS) were prepared and their properties were compared with those of the related complexes of (3-diphenylphosphino)benzenesulfonates. An X-ray crystal structure determination revealed that the para-sulfonated ligand has a Tolman cone angle slightly smaller than that of PPh3. It was established by pH-potentiometric measurements and by 1H and 31P NMR studies that the distribution of the hydride derivatives [RuClH(pTPPMS)3] and [RuH2(pTPPMS)3,4] is strongly pH-dependent. Hydrogenation of trans-cinnamaldehyde in aqueous-organic mixtures is catalyzed by [RuCl2(pTPPMS)4] and is also strongly influenced by the pH of the aqueous phase due to the pH-dependent formation of the above hydrides. In acidic solutions (pH < 2) an exclusive C=C reduction takes place, while in alkaline solutions (pH > 6) a selective C=O hydrogenation was observed.Key words: ruthenium, water soluble, hydrogenation, hydrides, sulfonated phosphines, biphasic.