Utilisation of water soluble iridium catalysts for signal amplification by reversible exchange-Reference-Cited by-同舟云学术

Utilisation of water soluble iridium catalysts for signal amplification by reversible exchange

Published:2015 Issue:17 Volume:44 Page:7870-7880
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fekete M.¹²³⁴,Gibard C.⁵⁶⁷⁸⁹,Dear G. J.¹⁰¹¹⁴,Green G. G. R.¹²³⁴,Hooper A. J. J.¹²³⁴,Roberts A. D.¹⁰¹¹⁴,Cisnetti F.⁵⁶⁷⁸⁹^ORCID,Duckett S. B.¹²³⁴

Affiliation:

1. Centre for Hyperpolarization in Magnetic Resonance

2. University of York

3. York

4. UK

5. Institut de Chimie de Clermont-Ferrand

6. Université Clermont Auvergne

7. Université Blaise Pascal and CNRS

8. F-63000 Clermont-Ferrand

9. France

10. GlaxoSmithKline Research & Development Limited

11. Hertfordshire

Abstract

The catalytic hyperpolarisation of pyridine, 3-hydroxypyridine and oxazol by the Signal Amplification By Reversible Exchange (SABRE) process is achieved by a series of water soluble iridium phosphine and N-heterocyclic carbene dihydride complexes.

Funder

Wellcome Trust

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00311C

Reference70 articles.

1. A Cationic Iridium Complex Bearing an Imidazol-2-ylidene Ligand as Alkene Hydrogenation Catalyst

2. Catalytic olefin hydrogenation using N-heterocyclic carbene–phosphine complexes of iridium

3. Transformation of Symmetrization Order to Nuclear-Spin Magnetization by Chemical Reaction and Nuclear Magnetic Resonance

4. Parahydrogen and synthesis allow dramatically enhanced nuclear alignment

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