Author:
Perrocheau Jacques,Carrié Robert,Fleury Jean-Pierre
Abstract
Thermolysis of 1,2,3-triazolines 4, 5, 6 leads to the corresponding aziridines only when X = Y = CO2Me, and then with a very low yield. However, photolysis or evolution in the presence of trifluoroacetic acid gives good results when carried out at sufficiently low temperature. The thermolysis study of 4–6 shows a new route to 1,2,3-triazoline decomposition that has not yet been mentioned in the literature. The easy elimination of the paratoluenesulfonate or benzoate group explains this particular behaviour.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
9 articles.
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