Investigation of benzoyloximes as benzoylating reagents: benzoyl-Oxyma as a selective benzoylating reagent

Author:

Burugupalli Satvika1234,Shah Sayali1234,van der Peet Phillip L.1234,Arora Seep1234,White Jonathan M.1234,Williams Spencer J.1234

Affiliation:

1. School of Chemistry and Bio21 Molecular Science and Biotechnology Institute

2. University of Melbourne

3. Parkville

4. Australia 3010

Abstract

Benzoyl-Oxyma is a highly crystalline, readily prepared, safer alternative to benzoyloxybenzotriazole, useful in the selective benzoylation of carbohydrate polyols.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference46 articles.

1. P. Wuts , Greene's Protective Groups in Organic Synthesis, John Wiley & Sons, New York, 5th edn, 2014

2. R. V. Stick and S. J.Williams, Carbohydrates: The Essential Molecules of Life, Elsevier, Oxford, United Kingdom, 2009

3. On the Role of Neighboring Group Participation and Ortho Esters in β-Xylosylation:  13C NMR Observation of a Bridging 2-Phenyl-1,3-dioxalenium Ion

4. Armed and disarmed n-pentenyl glycosides in saccharide couplings leading to oligosaccharides

5. A. H. Haines , in Adv. Carbohydr. Chem. Biochem, ed. R. S. Tipson and H. Derek, Academic Press, 1976, vol. 33, pp. 11–109

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