Author:
Janzen Edward G.,Stronks Henry J.,Nutter Jr. Dale E.,Davis Edward R.,Blount Henry N.,Poyer J. Lee,McCay Paul B.
Abstract
Azidyl, cyanatyl, and cyanyl radicals and chlorine atoms have been detected by spin trapping using α-phenyl N-tert-butyl nitrone (PBN) in the monoelectronic electrooxidations of azide, cyanate, cyanide, and chloride. Azidyl and cyanatyl radicals were also detected with PBN in the persulfate oxidations of azide and cyanate. Azidyl radicals could be detected in the reaction of azide with hydroxyl radicals in the presence of PBN.
Publisher
Canadian Science Publishing
Subject
Organic Chemistry,General Chemistry,Catalysis
Cited by
62 articles.
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